Journal article
Thermally stable zinc disalphen macrocycles showing solid-state and aggregation-induced enhanced emission
- Abstract:
-
In order to investigate the solid-state light emission of zinc salphen macrocycle complexes, 7 dinuclear zinc salphen macrocycle complexes (1-7), with acetate or hexanoate coligands, are synthesized. The complexes are stable in air up to 300 °C, as shown via thermogravimetric analysis (TGA), and exhibit green to orange-red emission in solution (λem = 550-600 nm, PLQE ≤ 1%) and slightly enhanced yellow to orange-red emission in the solid state (λem = 570-625 nm, PLQE = 1-5%). Complexes 1, 2, 4...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Accepted manuscript, pdf, 712.3KB)
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- Publisher copy:
- 10.1021/acs.inorgchem.7b00300
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Authors
Funding
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Inorganic Chemistry Journal website
- Volume:
- 56
- Issue:
- 10
- Pages:
- 5688–5695
- Publication date:
- 2017-04-25
- Acceptance date:
- 2017-04-11
- DOI:
- EISSN:
-
1520-510X
- ISSN:
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0020-1669
- Source identifiers:
-
691203
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:691203
- UUID:
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uuid:cc0d3579-191a-45fb-b4ba-69f367b65890
- Local pid:
- pubs:691203
- Deposit date:
- 2017-06-07
Terms of use
- Copyright holder:
- © 2017 American Chemical Society
- Copyright date:
- 2017
- Notes:
- This is the author accepted manuscript following peer review version of the article. The final version is available online from American Chemical Society at: 10.1021/acs.inorgchem.7b00300
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