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Thermally stable zinc disalphen macrocycles showing solid-state and aggregation-induced enhanced emission

Abstract:

In order to investigate the solid-state light emission of zinc salphen macrocycle complexes, 7 dinuclear zinc salphen macrocycle complexes (1-7), with acetate or hexanoate coligands, are synthesized. The complexes are stable in air up to 300 °C, as shown via thermogravimetric analysis (TGA), and exhibit green to orange-red emission in solution (λem = 550-600 nm, PLQE ≤ 1%) and slightly enhanced yellow to orange-red emission in the solid state (λem = 570-625 nm, PLQE = 1-5%). Complexes 1, 2, 4...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.inorgchem.7b00300

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More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
56
Issue:
10
Pages:
5688–5695
Publication date:
2017-04-25
Acceptance date:
2017-04-11
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Source identifiers:
691203
Language:
English
Keywords:
Pubs id:
pubs:691203
UUID:
uuid:cc0d3579-191a-45fb-b4ba-69f367b65890
Local pid:
pubs:691203
Deposit date:
2017-06-07

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