Journal article icon

Journal article

A Molecular Nanotube with Three-Dimensional π-Conjugation.

Abstract:

A π-conjugated twelve-porphyrin tube is synthesized in 32% yield by a template-directed coupling reaction that joins together six porphyrin dimers, forming twelve new C-C bonds. The nanotube has two bound templates, enclosing an internal volume of approximately 4.5 nm(3). Its UV/Vis/NIR absorption and fluorescence spectra resemble those of a previously reported six-porphyrin ring, but are red-shifted by approximately 300 cm(-1), reflecting increased conjugation. Ultrafast fluorescence spectro...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1002/anie.201502735

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More from this funder
Name:
Alexander von Humboldt Foundation
Funding agency for:
Neuhaus, P
Grant:
PIEF-GA-2011-301336
More from this funder
Name:
Marie Curie Individual Fellowship
Funding agency for:
Neuhaus, P
Grant:
PIEF-GA-2011-301336
More from this funder
Name:
European Research Council
Grant:
320969
More from this funder
Name:
Engineering and Physical Sciences Research Council
Publisher:
Wiley
Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
54
Issue:
25
Pages:
7344-7348
Publication date:
2015-05-07
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Language:
English
Keywords:
Pubs id:
pubs:523285
UUID:
uuid:cbaba7d1-4dba-4f7e-ae7a-6569f66bc62d
Local pid:
pubs:523285
Source identifiers:
523285
Deposit date:
2016-01-05

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP