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A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H.

Abstract:

The solid-state structure of the rhodium complex (dimethylamine-dimethylaminoborane-borane-κ(2)H,H')dihydridobis(triisopropylphosphane-κP)rhodium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, [RhH(2)(C(4)H(18)B(2)N(2))(C(9)H(21)P)(2)](C(32)H(12)BF(24)), is reported. The complex contains the linear diborazine H(3)B·NMe(2)BH(2)·NMe(2)H, a kinetically important intermediate in the transition-metal-mediated dehydrocoupling of H(3)B·NMe(2)H, ultimately affording the dimeric amino-borane [H(...

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Publication status:
Published

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Publisher copy:
10.1107/s0108270111043447

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Acta crystallographica. Section C, Crystal structure communications More from this journal
Volume:
67
Issue:
Pt 11
Pages:
m355-m358
Publication date:
2011-11-01
DOI:
EISSN:
1600-5759
ISSN:
0108-2701
Language:
English
Pubs id:
pubs:330960
UUID:
uuid:cac54d7b-5f99-4a68-98fa-b09ceb1ceda7
Local pid:
pubs:330960
Source identifiers:
330960
Deposit date:
2012-12-19

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