Journal article
Atomic scale imaging of reversible ring cyclization in graphene nanoconstrictions
- Abstract:
-
We present an atomic level study of reversible cyclization processes in suspended nanoconstricted regions of graphene that form linear carbon chains (LCCs). Before the nanoconstricted region reaches a single linear carbon chain (SLCC), we observe that a double linear carbon chain (DLCC) structure often reverts back to a ribbon of sp2 hybridized oligoacene rings, in a process akin to the Bergman rearrangement. When the length of the DLCC system only consists of ∼5 atoms in each LCC, full recyc...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
-
(Accepted manuscript, pdf, 2.1MB)
-
(Accepted manuscript, pdf, 1.2MB)
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- Publisher copy:
- 10.1021/acsnano.8b09211
Authors
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- ACS Nano Journal website
- Volume:
- 13
- Issue:
- 2
- Pages:
- 2379–2388
- Publication date:
- 2019-01-23
- Acceptance date:
- 2019-01-15
- DOI:
- ISSN:
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1936-0851 and 1936-086X
- Pmid:
-
30673212
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:965827
- UUID:
-
uuid:cac3d79d-a2a7-4105-84a8-cc369e6d36a9
- Local pid:
- pubs:965827
- Source identifiers:
-
965827
- Deposit date:
- 2019-01-30
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2019
- Rights statement:
- © 2019 American Chemical Society
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from American Chemical Society at: https://doi.org/10.1021/acsnano.8b09211
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