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Design of three-dimensional open-framework structures from inorganic clusters

Abstract:
A series of open-framework germanates and silicogermanates were synthesized (denoted as SU-n) hydro-/solvo-thermally. Their structures were built from a single or two types of inorganic clusters containing a number of well-defined Ge-O coordination polyhedra. Different arrangements and combinations of these clusters resulted in different open-framework structures including some germanate/silicogermanates with extra-large pores (16- 24 rings). Herein we present our recently discovered crystalline structures of SU-3, SU-8, SU-12, SU-44, SU-M and SU-MB. SU-M and SU-MB contain 30-ring channels and pores extending to the mesoporous range (> 20). © 2007 Elsevier B.V. All rights reserved.
Publication status:
Published

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Publisher copy:
10.1016/S0167-2991(07)80908-6

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
FROM ZEOLITES TO POROUS MOF MATERIALS: THE 40TH ANNIVERSARY OF INTERNATIONAL ZEOLITE CONFERENCE, PROCEEDINGS OF THE 15TH INTERNATIONAL ZEOLITE CONFERENCE More from this journal
Volume:
170
Issue:
A
Pages:
682-689
Publication date:
2007-01-01
DOI:
ISSN:
0167-2991


Language:
English
Pubs id:
pubs:321989
UUID:
uuid:ca4dc2dd-1a3e-4f81-892a-ada7b80bc28d
Local pid:
pubs:321989
Source identifiers:
321989
Deposit date:
2012-12-19

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