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Electrode processes with coupled chemistry. Heterogeneous or homogeneous chemical reaction? The reduction of nitromethane in basic aqueous solution

Abstract:
The reduction of nitromethane in aqueous solution (pH 8.3) at Au/Hg channel electrodes is suggested, by means of joint electrochemical ESR and voltammetric measurements, to follow an ECEEE mechanism in which the rate determining chemical step is a surface catalysed reaction. Theory characterising heterogeneous ECE (and ECEEE) processes at channel electrodes, studied voltammetrically and with in situ ESR detection, is reported. © 1997 Elsevier Science S.A.
Publication status:
Published

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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
437
Issue:
1-2
Pages:
183-189
Publication date:
1997-11-10
DOI:
ISSN:
0022-0728
URN:
uuid:ca333729-41ca-4059-acd5-694c65f5670b
Source identifiers:
36372
Local pid:
pubs:36372

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