Journal article

Electrode processes with coupled chemistry. Heterogeneous or homogeneous chemical reaction? The reduction of nitromethane in basic aqueous solution

Abstract:: The reduction of nitromethane in aqueous solution (pH 8.3) at Au/Hg channel electrodes is suggested, by means of joint electrochemical ESR and voltammetric measurements, to follow an ECEEE mechanism in which the rate determining chemical step is a surface catalysed reaction. Theory characterising heterogeneous ECE (and ECEEE) processes at channel electrodes, studied voltammetrically and with in situ ESR detection, is reported. © 1997 Elsevier Science S.A.

Publication status:: Published

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Cite

Cite this record

APA Style

Prieto, F., Webster, R., Alden, J., Aixill, W., Waller, G., Compton, R., & Rueda, M. (1997). Electrode processes with coupled chemistry. Heterogeneous or homogeneous chemical reaction? The reduction of nitromethane in basic aqueous solution. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 437(1-2), 183–189.

MLA Style

Prieto, F., et al. “Electrode Processes with Coupled Chemistry. Heterogeneous or Homogeneous Chemical Reaction? The Reduction of Nitromethane in Basic Aqueous Solution.” JOURNAL OF ELECTROANALYTICAL CHEMISTRY, vol. 437, no. 1-2, 1997, pp. 183–89.

Chicago Style

Prieto, F, R Webster, J Alden, W Aixill, G Waller, R Compton, and M Rueda. 1997. “Electrode Processes with Coupled Chemistry. Heterogeneous or Homogeneous Chemical Reaction? The Reduction of Nitromethane in Basic Aqueous Solution.” JOURNAL OF ELECTROANALYTICAL CHEMISTRY 437 (1-2): 183–89.
Share
Print

Access Document

Publisher copy:: 10.1016/S0022-0728(97)00324-0

Authors

+ Prieto, F More by this author

Role:: Author

+ Webster, R More by this author

Role:: Author

+ Alden, J More by this author

Role:: Author

+ Aixill, W More by this author

Role:: Author

+ Waller, G More by this author

Role:: Author

More authors...

Journal:: JOURNAL OF ELECTROANALYTICAL CHEMISTRY More from this journal
Volume:: 437
Issue:: 1-2
Pages:: 183-189
Publication date:: 1997-11-10
DOI:: 10.1016/S0022-0728(97)00324-0
ISSN:: 0022-0728

Language:: English
Keywords:: channel electrode

electrochemical ESR

nitromethane reduction mechanism

nitromethane radical anion

heterogeneous ECE mechanism
Pubs id:: pubs:36372
UUID:: uuid:ca333729-41ca-4059-acd5-694c65f5670b
Local pid:: pubs:36372
Source identifiers:: 36372
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 1997

Licence:: Terms and Conditions of Use for Oxford University Research Archive

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP