Electrode processes with coupled chemistry. Heterogeneous or homogeneous chemical reaction? The reduction of nitromethane in basic aqueous solution
- The reduction of nitromethane in aqueous solution (pH 8.3) at Au/Hg channel electrodes is suggested, by means of joint electrochemical ESR and voltammetric measurements, to follow an ECEEE mechanism in which the rate determining chemical step is a surface catalysed reaction. Theory characterising heterogeneous ECE (and ECEEE) processes at channel electrodes, studied voltammetrically and with in situ ESR detection, is reported. © 1997 Elsevier Science S.A.
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