Journal article
The alkaline hydrolysis of sulfonate esters: challenges in interpreting experimental and theoretical data
- Abstract:
-
Sulfonate ester hydrolysis has been the subject of recent debate, with experimental evidence interpreted in terms of both stepwise and concerted mechanisms. In particular, a recent study of the alkaline hydrolysis of a series of benzene arylsulfonates (Babtie et al., Org. Biomol. Chem.10, 2012, 8095) presented a nonlinear Brønsted plot, which was explained in terms of a change from a stepwise mechanism involving a pentavalent intermediate for poorer leaving groups to a fully concerted mechani...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Authors
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of Organic Chemistry Journal website
- Volume:
- 79
- Issue:
- 7
- Pages:
- 2816-2828
- Publication date:
- 2013-11-26
- DOI:
- EISSN:
-
1520-6904
- ISSN:
-
0022-3263
Item Description
- Language:
- English
- Pubs id:
-
1170222
- Local pid:
- pubs:1170222
- Deposit date:
- 2021-04-02
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2013
- Rights statement:
- © 2013 American Chemical Society.
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