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Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene.

Abstract:
A new bis(indenyl)zirconocene bearing a pendant Si-Cl anchor has been grafted onto MCM-41, SBA-15, MCM-48 and a disordered mesoporous silica for the polymerisation of ethylene and propylene, producing polymers with very high molecular weights, low polydispersities and, in the case of polypropylene, higher levels of isotacticity than obtainable with analogous homogeneous systems.
Publication status:
Published

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Publisher copy:
10.1039/b403043e

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Journal:
Chemical Communications More from this journal
Volume:
10
Issue:
15
Pages:
1710-1711
Publication date:
2004-08-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345


Language:
English
Pubs id:
pubs:51177
UUID:
uuid:c970fc18-f0f4-4479-b30d-5aa83a519eaf
Local pid:
pubs:51177
Source identifiers:
51177
Deposit date:
2012-12-19

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