Neutron studies of a high spin Fe-19 molecular nanodisc

Journal article

The molecular cluster system [Fe19(metheidi)10(OH)14O6(H2O)12]NO3·24H2O, abbreviated as Fe19, contains nineteen Fe(III) ions arranged in a disc-like structure with the total spin S = 35/2. For the first order, it behaves magnetically as a single molecule magnet with a 16 K anisotropy barrier. The high spin value enhances weak intermolecular interactions for both dipolar and superexchange mechanisms and an eventual transition to antiferromagnetic order occurs at 1.2 K. We used neutron diffraction to determine both the mode of ordering and the easy spin axis. The observed ordering was not consistent with a purely dipolar driven order, indicating a significant contribution from intermolecular superexchange. The easy axis is close to the molecular Fe1–Fe10 axis. Inelastic neutron scattering was used to follow the magnetic order parameter and to measure the magnetic excitations. Direct transitions to at least three excited states were found in the 2 to 3 meV region. Measurements below 0.2 meV revealed two low energy excited states, which were assigned to S = 39/2 and S = 31/2 spin states with respective excitation gaps of 1.5 and 3 K. Exchange interactions operating over distances of order 10 Å were determined to be on the order of 5 mK and were eight-times stronger than the dipolar coupling.

Authors: Pratt, FL; Guidi, T; Manuel, P; Anson, CE; Tang, J

• Publication status: Published
• Peer review status: Peer reviewed
• Publisher: MDPI
• Journal: Magnetochemistry
• Volume: 7
• Issue: 6
• Article number: 74
• Publication date: 2021-05-21
• Acceptance date: 2021-05-18
• DOI: 10.3390/magnetochemistry7060074
• EISSN: 2312-7481
• Language: English
• Keywords: FFR; single molecule magnet; neutron diffraction; Monte Carlo simulation; magnetic nanodisc; weak superexchange interactions; dipolar driven magnetism; high spin molecule; inelastic neutron scattering; magnetic molecular cluster