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Synthesis and structural characterization of Ba14Pd3Ir8O33

Abstract:

Ba14Pd3Ir8O33 has been prepared in polycrystalline form and characterized by X-ray, neutron and electron diffraction, lattice imaging and magnetometry. The structure can be described as the n=5,m=9 member of the (A3O9)n(A3A′O 6)m series which derives from the n=∞, m=0 2H perovskite structure. Ir and Pd cations occupy chains of octahedral and trigonal-prismatic sites in a disordered manner. An alternative description of the structure in (3+1)-dimensional superspace is also presented. No magnet...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF SOLID STATE CHEMISTRY More from this journal
Volume:
174
Issue:
1
Pages:
96-103
Publication date:
2003-08-01
DOI:
ISSN:
0022-4596
Language:
English
Keywords:
Pubs id:
pubs:38688
UUID:
uuid:c9145f45-0362-4a6f-8551-1b1a47029e9f
Local pid:
pubs:38688
Source identifiers:
38688
Deposit date:
2012-12-19

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