Journal article
Groups 1, 2 and Zn(II) heterodinuclear catalysts for epoxide/CO2 ring-opening copolymerization
- Abstract:
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A series of heterodinuclear complexes are reported where both Zn(II) and a metal from Group 1 or 2 are chelated by a macrocyclic diphenolate-tetra-amine ligand. The complexes are characterized in the solid state, where relevant by single crystal X-ray crystallography and elemental analysis, and in solution, using NMR spectroscopy and mass spectrometry. The complex synthesis is achieved by reaction of the ligand with diethyl zinc to form the monozinc complex, in situ, followed by subsequent co...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
-
(Accepted manuscript, pdf, 751.1KB)
-
- Publisher copy:
- 10.1021/acs.inorgchem.8b02923
Authors
Funding
Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Inorganic Chemistry Journal website
- Volume:
- 57
- Issue:
- 24
- Pages:
- 15575-15583
- Publication date:
- 2018-11-30
- Acceptance date:
- 2018-11-14
- DOI:
- EISSN:
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1520-510X
- ISSN:
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0020-1669
- Pmid:
-
30499670
Item Description
- Language:
- English
- Pubs id:
-
pubs:952213
- UUID:
-
uuid:c748effc-a838-48f1-b84d-e557e63ac5df
- Local pid:
- pubs:952213
- Source identifiers:
-
952213
- Deposit date:
- 2019-02-08
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2018
- Notes:
- Copyright © 2018 American Chemical Society. This is the accepted manuscript version of the article. The final version is available online from American Chemical Society at: https://doi.org/10.1021/acs.inorgchem.8b02923
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