Journal article
Influence of solvent quality on polymer solutions: a Monte Carlo study of bulk and interfacial properties.
- Abstract:
- The effect of solvent quality on dilute and semidilute regimes of polymers in solution is studied by means of Monte Carlo simulations. The equation of state, adsorption near a hard wall, wall-polymer surface tension, and effective depletion potential are all calculated as a function of concentration and solvent quality. We find important differences between polymers in good and theta solvents. In the dilute regime, the physical properties for polymers in a theta solvent closely resemble those of ideal polymers. In the semidilute regime, however, significant differences are found.
- Publication status:
- Published
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Authors
- Journal:
- Journal of chemical physics More from this journal
- Volume:
- 121
- Issue:
- 1
- Pages:
- 612-620
- Publication date:
- 2004-07-01
- DOI:
- EISSN:
-
1089-7690
- ISSN:
-
0021-9606
- Language:
-
English
- Pubs id:
-
pubs:153967
- UUID:
-
uuid:c6d88b76-795f-4a63-a678-a1281a94c426
- Local pid:
-
pubs:153967
- Source identifiers:
-
153967
- Deposit date:
-
2012-12-19
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- Copyright date:
- 2004
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