Journal article icon

Journal article

Influence of solvent quality on polymer solutions: a Monte Carlo study of bulk and interfacial properties.

Abstract:
The effect of solvent quality on dilute and semidilute regimes of polymers in solution is studied by means of Monte Carlo simulations. The equation of state, adsorption near a hard wall, wall-polymer surface tension, and effective depletion potential are all calculated as a function of concentration and solvent quality. We find important differences between polymers in good and theta solvents. In the dilute regime, the physical properties for polymers in a theta solvent closely resemble those of ideal polymers. In the semidilute regime, however, significant differences are found.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1063/1.1756571

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Theoretical Physics
Role:
Author


Journal:
Journal of chemical physics More from this journal
Volume:
121
Issue:
1
Pages:
612-620
Publication date:
2004-07-01
DOI:
EISSN:
1089-7690
ISSN:
0021-9606


Language:
English
Pubs id:
pubs:153967
UUID:
uuid:c6d88b76-795f-4a63-a678-a1281a94c426
Local pid:
pubs:153967
Source identifiers:
153967
Deposit date:
2012-12-19

Terms of use



Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP