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A new class of alumina-forming superalloy for 3D printing

Abstract:
A new class of crack-resistant nickel-based superalloy containing high 𝛾′ fraction is studied for the laser-powder bed fusion (L-PBF) process. The effects of the (Nb+Ta)/Al ratio is emphasized, a strategy that is shown to confer excellent low-temperature strength whilst maintaining oxidation resistance at high temperatures via stable alumina scale formation. The processability of the new alloys is characterized with respect to defect assessment by micro-focus X-ray computed tomography; use is made of a prototype turbine blade geometry and the heritage alloy CM247LC as a benchmark. In all cases, some processing-related porosity is present in thin wall sections such as the trailing edge, but this can be avoided by judicious processing. The cracking seen in CM247LC – in solid-state, liquation and solidification forms – is avoided. A novel sub-solvus heat treatment strategy is proposed which takes advantage of AM not requiring solutioning; super-solvus heat treatment is inappropriate since it embrittles the material by deterioration of the texture and coarsening of grain boundary carbides. The tensile strength of the new superalloy is greatest when the Nb+Ta content is highest and exceeds that of CM247LC up to ∼900 ◦C. The oxidation resistance is best when Al content is highest, and oxidation-assisted cracking resistance maximized when the (Nb+Ta)/Al ratio is balanced. In all cases these are equivalent or superior to that of CM247LC. Nevertheless, the creep resistance of the new alloys is somewhat inferior to that of CM247LC for which the 𝛾′, C, and B contents are higher; this implies a processing/property trade-off which requires further clarification.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.addma.2022.102608

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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
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Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author
ORCID:
0000-0002-6871-3221
More by this author
Role:
Author
ORCID:
0000-0002-7755-4947
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Role:
Author
ORCID:
0000-0002-8458-1038
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Materials
Role:
Author


Publisher:
Elsevier
Journal:
Additive Manufacturing More from this journal
Volume:
52
Article number:
102608
Publication date:
2022-02-05
Acceptance date:
2022-01-06
DOI:
EISSN:
2214-8604
ISSN:
2214-7810


Language:
English
Keywords:
Pubs id:
1238628
Local pid:
pubs:1238628
Deposit date:
2022-02-18
ARK identifier:

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