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Linear relationship between activation energies and reaction energies for coverage-dependent dissociation reactions on rhodium surfaces.

Abstract:

Evidence of a relationship between activation energies and enthalpy changes of various dissociation reactions on transition metals has been reported recently. A reconsideration of density functional theory results for dissociation energies of oxygen and NO on different rhodium surfaces (low-index and stepped) and their dependencies on oxygen precoverage reveal that also here a linear Brønsted-Evans-Polanyi (BEP) relationship exists. The establishment of such a general concept would be of trem...

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Publisher copy:
10.1039/b506773a

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry
Role:
Author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
7
Issue:
13
Pages:
2552-2553
Publication date:
2005-07-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:c5ebb829-43cd-478e-ac9e-c7fb2be9eb4c
Source identifiers:
267345
Local pid:
pubs:267345

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