Journal article
Experimental validation of Marcus theory for outer-sphere heterogeneous electron-transfer reactions: the oxidation of substituted 1,4-phenylenediamines.
- Abstract:
- Rate constants depend on molecular size: Results are presented to validate the relationship between molecular size and the standard electrochemical rate constant predicted by Marcus theory (see graphic). Measurement of hydrodynamic radii and electron-transfer rates for substituted 1,4-phenylenediamines have been made under steady-state conditions using both hydrodynamic and stationary electrodes.
- Publication status:
- Published
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- Publisher copy:
- 10.1002/cphc.200400128
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Authors
Bibliographic Details
- Journal:
- Chemphyschem : a European journal of chemical physics and physical chemistry
- Volume:
- 5
- Issue:
- 8
- Pages:
- 1234-1240
- Publication date:
- 2004-08-01
- DOI:
- EISSN:
-
1439-7641
- ISSN:
-
1439-4235
- Source identifiers:
-
32854
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:32854
- UUID:
-
uuid:c4dc8634-00bc-4497-a11f-6db44865adf2
- Local pid:
- pubs:32854
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2004
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