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Experimental validation of Marcus theory for outer-sphere heterogeneous electron-transfer reactions: the oxidation of substituted 1,4-phenylenediamines.

Abstract:
Rate constants depend on molecular size: Results are presented to validate the relationship between molecular size and the standard electrochemical rate constant predicted by Marcus theory (see graphic). Measurement of hydrodynamic radii and electron-transfer rates for substituted 1,4-phenylenediamines have been made under steady-state conditions using both hydrodynamic and stationary electrodes.
Publication status:
Published

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Publisher copy:
10.1002/cphc.200400128

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Chemphyschem : a European journal of chemical physics and physical chemistry
Volume:
5
Issue:
8
Pages:
1234-1240
Publication date:
2004-08-05
DOI:
EISSN:
1439-7641
ISSN:
1439-4235
URN:
uuid:c4dc8634-00bc-4497-a11f-6db44865adf2
Source identifiers:
32854
Local pid:
pubs:32854

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