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η8-Permethylpentalene Titanium Chemistry

Abstract:

The focus of this thesis is the synthesis of organometallic complexes incorporating the η8-permethylpentalene titanium moiety (η8-Pn*Ti), their characterisation, and their reactivity with small molecules. Chapter One summarises the chemistry of the pentalene molecule, from its instability in the free state to the incorporation of the hydrocarbon into organometallic complexes. The chapter continues with a review of the coordination modes available to Pn and concludes with ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Research group:
Prof. Dermot O'Hare
Oxford college:
Lincoln College
Role:
Author

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Division:
MPLS
Department:
Chemistry
Role:
Supervisor
Publication date:
2012
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
Language:
English
Keywords:
Subjects:
UUID:
uuid:c4c3911b-1924-4e2f-a750-d07599900756
Local pid:
ora:9636
Deposit date:
2014-12-22

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