Journal article

Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch.

Abstract:: It's all in the ligand: By choice of the appropriate diphosphine ligand a previously linear-selective alkyne hydroacylation process can be "switched" to be highly branched-selective (see scheme, l=linear, b=branched). Structural data for the ortho-iPr-dppe-rhodium catalyst suggest restricted rotation of the phosphine aryl units may be responsible for the observed selectivity. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.

Publication status:: Published

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APA Style

González-Rodríguez, C., Pawley, R., Chaplin, A. B., Thompson, A., Weller, A., & Willis, M. (2011). Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. Angewandte Chemie (International Ed. in English), 50(22), 5134–5138.

MLA Style

González-Rodríguez, C., et al. “Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: a Ligand-Controlled Regioselectivity Switch.” Angewandte Chemie (International Ed. in English), vol. 50, no. 22, 2011, pp. 5134–38.

Chicago Style

González-Rodríguez, C, R Pawley, AB Chaplin, A Thompson, A Weller, and M Willis. 2011. “Rhodium-Catalyzed Branched-Selective Alkyne Hydroacylation: a Ligand-Controlled Regioselectivity Switch.” Angewandte Chemie (International Ed. in English) 50 (22): 5134–38.
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Publisher copy:: 10.1002/anie.201100956

Authors

+ González-Rodríguez, C More by this author

Role:: Author

+ Pawley, R More by this author

Role:: Author

+ Chaplin, AB More by this author

Role:: Author

+ Thompson, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

More authors...

Journal:: Angewandte Chemie (International ed. in English) More from this journal
Volume:: 50
Issue:: 22
Pages:: 5134-5138
Publication date:: 2011-05-01
DOI:: 10.1002/anie.201100956
EISSN:: 1521-3773
ISSN:: 1433-7851

Language:: English
Keywords:: alkynes

hydroacylation

regioselectivity

rhodium catalysis
Pubs id:: pubs:134971
UUID:: uuid:c45ef674-864b-4eea-b64d-a80ec33c49c0
Local pid:: pubs:134971
Source identifiers:: 134971
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2011

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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