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Exploring template-bound dinuclear copper porphyrin nanorings by EPR spectroscopy

Abstract:

Electron paramagnetic resonance (EPR) spectroscopy has been used to study the molecular geometry as well as metal–ligand interactions in ten-membered porphyrin nanorings (c-P10Cu2) containing two copper and eight zinc centers. The presence of copper in the structures allows intramolecular interactions, including dipolar interactions between electron spins and hyperfine interactions to be quantified. Results obtained for c-P10Cu2 samples bound to two molecular templates with four or five bindi...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1039/C6SC01810F

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Chemistry Research Laboratory
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Science Journal website
Publication date:
2016
DOI:
ISSN:
2041-6539
URN:
uuid:c295c695-a5b5-465f-ab22-094e3327f09b
Source identifiers:
636275
Local pid:
pubs:636275

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