- Abstract:
-
Lithium–oxygen cells in which lithium peroxide forms in solution rather than on the electrode surface, can sustain relatively high cycling rates but require redox mediators to charge. The mediators are oxidised at the electrode surface and then oxidise lithium peroxide stored in the cathode. The kinetics of lithium peroxide oxidation has received almost no attention and yet are crucial for operation of the lithium–oxygen cell. It is essential that the molecules oxidise lithium peroxide suffic...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 544.0KB)
-
- Publisher copy:
- 10.1038/s41467-018-03204-0
-
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- Publisher:
- Springer Nature Publisher's website
- Journal:
- Nature Communications Journal website
- Volume:
- 9
- Pages:
- Article: 767
- Publication date:
- 2018-02-22
- Acceptance date:
- 2018-01-29
- DOI:
- EISSN:
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2041-1723
- ISSN:
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2041-1723
- Pubs id:
-
pubs:822880
- URN:
-
uri:c23a0cc0-55b5-455f-bb68-a14d8ea2e3bc
- UUID:
-
uuid:c23a0cc0-55b5-455f-bb68-a14d8ea2e3bc
- Local pid:
- pubs:822880
- Copyright holder:
- Chen et al.
- Copyright date:
- 2018
- Notes:
- Author(s) retain copyright; published by Nature Publishing Group under a Creative Commons Attribution 4.0 International License.
Journal article
Kinetics of lithium peroxide oxidation by redox mediators and consequences for the lithium-oxygen cell
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