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Thermal analog of gimbal lock in a colloidal ferromagnetic Janus rod

Abstract:
We report an entropy-driven orientational hopping transition in a magnetically confined colloidal Janus rod. In a magnetic field, the sedimented rod randomly hops between horizontal and vertical states: the latter state comes at a substantial gravitational cost at no reduction of magnetic potential energy. The probability distribution over the angles of the rod shows that the presence of an external magnetic field leads to the emergence of a metastable vertical state separated from the ground state by an effective barrier. This barrier does not come from the potential energy but rather from the vast gain in phase space available to the rod as it approaches the vertical state. The loss of rotational degree of freedom that gives rise to this effect is a statistical mechanical analogue of the phenomenon of gimbal lock from classical mechanics.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1103/PhysRevLett.115.248301

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Theoretical Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Theoretical Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


More from this funder
Funding agency for:
Gao, Y
Grant:
Marie Curie actions (FP7-PEOPLE-2012-IIF No. 327919
More from this funder
Funding agency for:
Yeomans, J
Grant:
291234 MiCE
More from this funder
Funding agency for:
Balin, A
Dullens, R
Aarts, D
Grant:
EP/J001902/1
EP/J001902/1


Publisher:
American Physical Society
Journal:
Physical Review Letters More from this journal
Volume:
115
Issue:
24
Article number:
248301
Publication date:
2015-01-01
DOI:
ISSN:
1079-7114


Pubs id:
pubs:580321
UUID:
uuid:c169d9bb-d03f-4d07-ae94-0691fa6c63e1
Local pid:
pubs:580321
Source identifiers:
580321
Deposit date:
2015-12-21

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