Journal article
Synthesis of five-porphyrin nanorings by using ferrocene and corannulene templates
- Abstract:
- The smallest and most strained member of a family of π-conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl templates based on ferrocene and corannulene. Both templates are effective for directing the synthesis of the butadiyne-linked cyclic pentamer, despite the fact that the radii of their N5 donor sets are too small by 0.5 Å and 0.9 Å, respectively (from DFT calculations). The five-porphyrin nanoring exhibits a structured absorption spectrum and its fluorescence extends to 1200 nm, reflecting strong π conjugation and Herzberg-Teller vibronic coupling.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Version of record, zip, 25.9KB, Terms of use)
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- Publisher copy:
- 10.1002/anie.201602909
Authors
+ Kyushu University Leading Program for “Molecular System for Devices” from MEXT Japan
More from this funder
- Funding agency for:
- Hisamune, Y
- Publisher:
- Wiley
- Journal:
- Angewandte Chemie International Edition More from this journal
- Volume:
- 55
- Issue:
- 29
- Pages:
- 8358-8362
- Publication date:
- 2016-05-23
- Acceptance date:
- 2016-04-14
- DOI:
- EISSN:
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1521-3773
- ISSN:
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1433-7851
- Language:
-
English
- Keywords:
- Pubs id:
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pubs:625194
- UUID:
-
uuid:c151ba7c-a44a-4271-b831-fc1cd95f6d70
- Local pid:
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pubs:625194
- Source identifiers:
-
625194
- Deposit date:
-
2016-06-10
Terms of use
- Copyright holder:
- Liu et al
- Copyright date:
- 2016
- Notes:
- © 2016 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License.
- Licence:
- CC Attribution (CC BY)
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