Journal article
Ni(2,2′:6′,2′′-terpyridine) 2: a high-spin octahedral formal Ni(0) complex †
- Abstract:
- We have synthesised and characterised the complex Ni(tpy)2 (tpy = 2,2′:6′,2′′-terpyridine). This formally Ni(0) complex is paramagnetic both in the solid state and in solution (S = 2). The crystal structure shows an octahedral geometry, with molecules arranged in independent dimers involving π-stacking between pairs of complexes. Magnetic measurementes and DFT calculations suggest the existence of temperature-dependent intermolecular antiferromagnetic coupling in the solid state.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Version of record, pdf, 971.9KB, Terms of use)
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- Publisher copy:
- 10.1039/d3dt04247b
Authors
+ Ministry of Science and Information
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- Funder identifier:
- https://ror.org/05r0vyz12
- Publisher:
- Royal Society of Chemistry
- Journal:
- Dalton Transactions More from this journal
- Publication date:
- 2024-05-01
- Acceptance date:
- 2024-04-16
- DOI:
- EISSN:
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1477-9234
- ISSN:
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1477-9226
- Language:
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English
- Pubs id:
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1997073
- Local pid:
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pubs:1997073
- Source identifiers:
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1950485
- Deposit date:
-
2024-07-20
- ARK identifier:
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- Copyright date:
- 2024
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