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A highly distorted open-shell endohedral Zintl cluster: [Mn@Pb12]3-.

Abstract:

Reaction of an ethylenediamine (en) solution of K(4)Pb(9) and 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) with a tetrahydrofuran (THF) solution of Mn(3)(Mes)(6) (Mes = 2,4,6-trimethylphenyl) yielded the anionic cluster [Mn@Pb(12)](3-). This species was observed in the positive and negative ion-mode electrospray mass-spectra of the crude reaction mixture. The crystalline samples obtained from such solutions allowed us to confirm the composition of the sample as [K(...

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Publication status:
Published

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Publisher copy:
10.1021/ic200329m

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
50
Issue:
17
Pages:
8028-8037
Publication date:
2011-09-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:bfa57329-8656-4dde-b470-f15ef988d4b8
Source identifiers:
177445
Local pid:
pubs:177445
Language:
English

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