Journal article
A highly distorted open-shell endohedral Zintl cluster: [Mn@Pb12]3-.
- Abstract:
-
Reaction of an ethylenediamine (en) solution of K(4)Pb(9) and 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) with a tetrahydrofuran (THF) solution of Mn(3)(Mes)(6) (Mes = 2,4,6-trimethylphenyl) yielded the anionic cluster [Mn@Pb(12)](3-). This species was observed in the positive and negative ion-mode electrospray mass-spectra of the crude reaction mixture. The crystalline samples obtained from such solutions allowed us to confirm the composition of the sample as [K(...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/ic200329m
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Bibliographic Details
- Journal:
- Inorganic chemistry
- Volume:
- 50
- Issue:
- 17
- Pages:
- 8028-8037
- Publication date:
- 2011-09-01
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- Source identifiers:
-
177445
Item Description
- Language:
- English
- Pubs id:
-
pubs:177445
- UUID:
-
uuid:bfa57329-8656-4dde-b470-f15ef988d4b8
- Local pid:
- pubs:177445
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2011
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