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A new perspective: imaging the stereochemistry of molecular collisions.

Abstract:
The concept of the steric effect in molecular collisions is central to chemistry. In this Perspective article we review some of the progress made in studying the steric effect in inelastic and reactive collisions involving relatively small isolated atomic and molecular species. We overview the theoretical framework used to quantify the steric effect, and outline some of the key experimental approaches that can be employed to study the dynamics and mechanism of collisions involving oriented and alignment molecules. We illustrate the discussion by highlighting a few recent studies of inelastic and reactive scattering. Finally, we conclude with some reflections on possible future directions of interest.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c5cp03273c

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


More from this funder
Funding agency for:
Brouard, M
Gordon, S
Grant:
238671
More from this funder
Funding agency for:
Brouard, M
Gordon, S
Grant:
238671
More from this funder
Funding agency for:
Brouard, M
Grant:
238671


Publisher:
Royal Society of Chemistry
Journal:
Physical Chemistry Chemical Physics More from this journal
Volume:
17
Issue:
45
Pages:
30210-30228
Publication date:
2015-08-17
Acceptance date:
2015-08-12
DOI:
EISSN:
1463-9084
ISSN:
1463-9076


Language:
English
Pubs id:
pubs:575144
UUID:
uuid:bf1f17fd-5105-4e05-a320-ca1de2b91409
Local pid:
pubs:575144
Source identifiers:
575144
Deposit date:
2016-04-01

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