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(1RS,4SR)-3-Dichloro-methyl-ene-1,4-dimethyl-2-oxabicyclo-[2.2.2]oct-5-ene.

Abstract:
X-ray crystallography was used to confirm the structure of the enantio-enriched title compound, C(10)H(12)Cl(2)O, a bicylic enol ether. A bridged boat-like structure is adopted and the dichloro-methyl-ene C atom is positioned significantly removed from the core bicyclic unit. In the crystal structure, mol-ecules pack to form sheets approximately perpendicular to the a and c axes.
Publication status:
Published

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Publisher copy:
10.1107/s1600536808017248

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Journal:
Acta crystallographica. Section E, Structure reports online More from this journal
Volume:
64
Issue:
Pt 7
Pages:
o1261
Publication date:
2008-01-01
DOI:
EISSN:
1600-5368
ISSN:
1600-5368


Language:
English
Pubs id:
pubs:55221
UUID:
uuid:bda8c59f-fc8c-43cb-87e2-8baa0d9e6248
Local pid:
pubs:55221
Source identifiers:
55221
Deposit date:
2012-12-19

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