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Synthesis, characterisation and structure of a strained ring-tilted bis(indenyl)iron complex

Abstract:

The new bridged ligand (C9Me6H)2SiMe2 9 has been prepared and used to synthesise the first strained ansa-bridged bis(indenyl)iron complex Fe(η5-C9Me6)2SiMe2 11. The properties of 11 are compared with those of other SiMe2-bridged [1]-ferrocenophanes and with the unbridged analogue Fe(η5-C9Me6H)2 8. UV-vis and 13C NMR data are consistent with a ring-tilted structure for 11; the strain in the molecule is demonstrated by the observation of alcoholysis and hydrolysis products in its FAB mass spect...

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Publication status:
Published

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Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
528
Issue:
1-2
Pages:
47-58
Publication date:
1997-02-01
DOI:
ISSN:
0022-328X
URN:
uuid:bd05df31-4bfa-4d29-bbf8-7f98ced90dcc
Source identifiers:
51438
Local pid:
pubs:51438

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