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Excitons in the strong coupling limit of the one-dimensional extended Hubbard model

Abstract:
Excitons in the strong coupling limit of the half-filled one-dimensional extended Hubbard model with 1/r interactions are studied. Unlike the situation for nearest neighbor interactions, where there is at most only one (doubly degenerate) bound state, a 1/r interaction results in an infinite number of doubly degenerate bound states. In the continuum limit the exciton states are one-dimensional hydrogenlike states, with binding energies ∼ 1/n2. The particle-hole separation grows rapidly with n as n2. The binding energies are reduced on a discrete lattice. However, for conjugated systems of interest, the discrete correction to the continuum limit are small. When the infinite onsite repulsion limit is relaxed the degenerate states split, forming a doublet of even and odd parity states.
Publication status:
Published

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Publisher copy:
10.1103/PhysRevB.65.205118

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
Physical Review B More from this journal
Volume:
65
Issue:
20
Pages:
2051181-2051185
Publication date:
2002-05-15
DOI:
EISSN:
1095-3795
ISSN:
1098-0121


Language:
English
Pubs id:
pubs:38305
UUID:
uuid:bc35a2fc-68fb-4337-8b23-ccdc8de785f5
Local pid:
pubs:38305
Source identifiers:
38305
Deposit date:
2012-12-19

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