Journal article
The clusters Cd-2(2+) and Cd-4(2+) in zeolite A
- Abstract:
- The sorption of the vapour of elemental cadmium and zinc into Cd2+ ion-exchanged zeolite A leads to the formation of two cluster cations Cd22+ and Cd42+. Raman bands at 29, 81 and 114 cm-1 are assigned to a Cd42+ cluster; the less abundant Cd22+ is identified by its UV band at 226 nm. These Cdx2+ clusters are promising building blocks for the fabrication of heavy-metal atomic-scale quantum wires in the intracrystalline voids and channels of zeolite hosts.
- Publication status:
- Published
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Authors
- Journal:
- CHEMICAL PHYSICS LETTERS More from this journal
- Volume:
- 292
- Issue:
- 1-2
- Pages:
- 137-142
- Publication date:
- 1998-07-31
- DOI:
- ISSN:
-
0009-2614
- Language:
-
English
- Pubs id:
-
pubs:46298
- UUID:
-
uuid:babdddb9-20ea-4782-8e8e-a716ef600490
- Local pid:
-
pubs:46298
- Source identifiers:
-
46298
- Deposit date:
-
2012-12-19
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- Copyright date:
- 1998
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