Journal article
Fluoride degradable and thermally debondable polyurethane based adhesive
- Abstract:
-
We report the one-pot, solvent free synthesis of a stimuli-responsive polyurethane (PU) adhesive. The hard domains within the supramolecular PU network contain a silyl protected phenol ‘degradable unit’ (DU). The DU undergoes rapid decomposition (<30 minutes) upon treatment with fluoride ions which causes depolymerisation of the linear PU adhesive. The mechanism of depolymerisation was investigated in solution using 1H NMR spectroscopy by following the degradation of the polymer in the pre...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Accepted manuscript, pdf, 1.8MB)
-
(Accepted manuscript, pdf, 1.2MB)
-
- Publisher copy:
- 10.1039/C7PY01653K
Authors
Funding
+ Engineering and Physical Sciences Research Council
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Funding agency for:
Babra, T
+ Air Force Office of Scientific Research, Air Force Material Command, USAF
More from this funder
Funding agency for:
Trivedi, A
Grant:
FA9550-15-1-0448
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Polymer Chemistry Journal website
- Volume:
- 46
- Issue:
- 8
- Pages:
- 7207-7216
- Publication date:
- 2017-11-14
- Acceptance date:
- 2017-11-05
- DOI:
- EISSN:
-
1759-9962
- ISSN:
-
1759-9954
- Source identifiers:
-
745710
Item Description
- Pubs id:
-
pubs:745710
- UUID:
-
uuid:b98d2509-e3ec-4563-8ded-2853c156a55d
- Local pid:
- pubs:745710
- Deposit date:
- 2017-11-14
Terms of use
- Copyright holder:
- Babra, et al
- Copyright date:
- 2017
- Notes:
- © Babra, et al 2017. This is the author accepted manuscript following peer review version of the article. The final version is available online from Royal Society of Chemistry at: 10.1039/C7PY01653K
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