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Direct catalytic conversion of biomass-derived furan and ethanol to ethylbenzene

Abstract:

Herein, we report a synthetic strategy to convert biomass-derived unsubstituted furan to aromatics at high selectivity, especially to ethylbenzene via alkylation/Diels-Alder cycloaddition using ethanol, while greatly reducing the formation of the main side product, benzofuran, over zeolite catalysts. Using synchrotron X-ray powder diffraction and first principles calculations, it is shown that the above methodology favors the formation of aromatic products due to readily alkylation of furan b...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1021/acscatal.7b03952

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Kostetskyy, P More by this author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
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Science without Borders Brazil More from this funder
Brazilian National Council for Scientific and Technological Development More from this funder
Office of China Postdoctoral Council More from this funder
American Chemical Society Petroleum Research Fund More from this funder
University of Pittsburgh More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
ACS Catalysis Journal website
Publication date:
2018-01-10
Acceptance date:
2018-01-10
DOI:
EISSN:
2155-5435
Pubs id:
pubs:817441
URN:
uri:b6852d1c-9348-4696-b4b2-8b03a78416be
UUID:
uuid:b6852d1c-9348-4696-b4b2-8b03a78416be
Local pid:
pubs:817441

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