Chemical feedbacks during magma degassing control chlorine partitioning and metal extraction in volcanic arcs

Journal article

Knowledge of the architecture of active magmatic systems is important for both volcanic hazard assessment and evaluating potential geothermal energy production and metals recovery from magmatic fluids. Increasingly, magmatic systems are imaged using the magnetotelluric method to detect electrically conductive partial melt and/or saline magmatic fluid reservoirs. We review recent magnetotelluric studies at eight Andean volcanoes, revealing electrical conductivity anomalies with variable magnitudes and locations. Six of the studied volcanoes exhibit three main electrical conductivity anomalies, located at shallow (<3 km), intermediate (=5 km), and deep (>10 km) depths. The shallow anomalies are often thin and laterally extensive, consistent with clay cap alteration layers, while the deep anomalies are generally interpreted as partial melt reservoirs. The intermediate depth anomalies, although also often attributed to partial melt, have less clear origins. By analysing laboratory-derived electrical conductivity relationships, we show that the intermediate depth anomalies are generally most consistent with saline magmatic fluids stored in porous rock. However, other geophysical and petrological data suggest that localised partial melt also exists at intermediate depths. Therefore, the intermediate depth anomalies likely represent mixed melt and saline magmatic fluid systems, such as those responsible for forming magmatic-hydrothermal alteration zones and copper porphyry deposits. At individual volcanoes, refining the generalised three layer model proposed here by using additional geophysical or petrological data is key to constraining the resources and/or hazard potential of the magmatic system

Authors: Tattitch, B; Chelle-Michou, C; Blundy, J; Loucks, RR

• Publication status: Published
• Peer review status: Peer reviewed
• Publisher: Nature Research
• Journal: Nature Communications
• Volume: 12
• Issue: 1
• Pages: 1774-1774
• Article number: 1774
• Publication date: 2021-03-19
• DOI: 10.1038/s41467-021-21887-w
• EISSN: 2041-1723
• ISSN: 2041-1723
• Language: English
• Keywords: Hydrothermal circulation; Mineralization (soil science); Copper; Magma chamber; Igneous differentiation; Fluid inclusions; Petrology; Melt inclusions; Magmatism; Seismology; Tectonics; Geology; Magmatic water; Geochemistry; Chemistry; Porphyry copper deposit; Volcanic rock; Volcano; Magma