Journal article
Exploiting trans ‐Sulfinylation for the Synthesis of Diverse N ‐Alkyl Sulfinamides via Decarboxylative Sulfinamidation
- Abstract:
- Combining simple amines with the bench‐stable sulfinylamine Tr‐NSO allows in situ preparation of reactive alkyl sulfinylamines, which when combined with alkyl radicals generated by photocatalytic decarboxylation, provides N‐alkyl sulfinamides. The reactions are broad in scope and tolerate a wide variety of functional groups on both the acid and amine components. The sulfinamide products are used to prepare a selection of challenging S(VI) products. The method provides a convenient way to use reactive and unstable alkyl sulfinylamines.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Preview, Version of Record, Version of record, pdf, 4.2MB, Terms of use)
-
- Publisher copy:
- 10.1002/ange.202407970
Authors
+ Engineering and Physical Sciences Research Council
More from this funder
- Funder identifier:
- https://ror.org/0439y7842
- Publisher:
- Wiley
- Journal:
- Angewandte Chemie More from this journal
- Article number:
- e202407970
- Publication date:
- 2024-08-22
- DOI:
- ISSN:
-
0044-8249, 1521-3757
- Language:
-
English
- Keywords:
- Pubs id:
-
2016116
- Local pid:
-
pubs:2016116
- Source identifiers:
-
2206623
- Deposit date:
-
2024-08-22
- ARK identifier:
This ORA record was generated from metadata provided by an external service. It has not been edited by the ORA Team.
Terms of use
- Copyright date:
- 2024
- Licence:
- CC Attribution (CC BY)
If you are the owner of this record, you can report an update to it here: Report update to this record