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Unconventional reactivity of ethynylbenziodoxolone reagents and thiols: scope and mechanism

Abstract:

1,2-Dithio-1-alkenes are biologically active compounds widely implemented throughout organic synthesis, functional materials, coordination chemistry, and pharmaceuticals. Traditional methods for accessing 1,2-dithio-1-alkenes often demand transition metal catalysts, specialized or air-sensitive ligands, high temperatures, and disulfides (R2 S2 ). Herein, a general and efficient strategy utilizing ethynylbenziodoxolone (EBX) reagents and thiols is presented that results in the formation of 1,2...

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Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1002/chem.201904520

Authors


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Role:
Author
ORCID:
0000-0001-7042-2901
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Oxford college:
St Hilda's College
Role:
Author
ORCID:
0000-0002-0104-4166
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Role:
Author
ORCID:
0000-0003-2451-7090
National Science Foundation More from this funder
Publisher:
Wiley Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
26
Issue:
11
Pages:
2386-2394
Publication date:
2020-01-22
Acceptance date:
2019-10-27
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
Pmid:
31657063
Language:
English
Keywords:
Pubs id:
1084293
Local pid:
pubs:1084293
Deposit date:
2020-07-30

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