Journal article
Synthesis of metallophosphaalkenes by reaction of organometallic nucleophiles with a phosphaethynolato-borane
- Abstract:
- We describe the reaction of a phosphaethynolato-borane [B]OCP ([B] = N,N′-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaboryl) with the organometallic nucleophile Na[Cp*Fe(CO)2] (Cp* = pentamethylcyclopentadienyl). The electrophilic character of [B]OCP allows for a new route towards the formation metal–phosphorus bonds affording a metallophosphaalkene that can be functionalised at both the oxygen and phosphorus atoms depending on the reagents employed.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
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(Preview, Not applicable (or unknown), pdf, 822.4KB, Terms of use)
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(Not applicable (or unknown), x-cif, 199.0KB, Terms of use)
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(Preview, Accepted manuscript, pdf, 687.7KB, Terms of use)
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- Publisher copy:
- 10.1039/c9cc03040a
Authors
- Publisher:
- Royal Society of Chemistry
- Journal:
- Chemical Communications More from this journal
- Volume:
- 55
- Issue:
- 48
- Pages:
- 6842-6845
- Publication date:
- 2019-05-14
- Acceptance date:
- 2019-05-14
- DOI:
- EISSN:
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1364-548X
- ISSN:
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1359-7345
- Pmid:
-
31120468
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:1003293
- UUID:
-
uuid:b41e2a5a-7208-421b-b7da-67b333dd2fcb
- Local pid:
-
pubs:1003293
- Source identifiers:
-
1003293
- Deposit date:
-
2019-05-31
- ARK identifier:
Terms of use
- Copyright holder:
- Wilson and Goicoechea
- Copyright date:
- 2019
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from the Royal Society of Chemistry at https://doi.org/10.1039/C9CC03040A
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