Journal article
Exchange of coordinated solvent during crystallisation of a metal-organic framework observed by in situ high energy X-ray diffraction.
- Abstract:
- Using time-resolved monochromatic high energy X-ray diffraction, we present an in situ study of the solvothermal crystallisation of a new MOF [Yb2 (BDC)3 (DMF)2 ]⋅H2 O (BDC=benzene-1,4-dicarboxylate and DMF=N,N-dimethylformamide) under solvothermal conditions, from mixed water/DMF solvent. Analysis of high resolution powder patterns obtained reveals an evolution of lattice parameters and electron density during the crystallisation process and Rietveld analysis shows that this is due to a gradual topochemical replacement of coordinated solvent molecules. The water initially coordinated to Yb(3+) is replaced by DMF as the reaction progresses.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Accepted manuscript, pdf, 1.1MB, Terms of use)
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- Publisher copy:
- 10.1002/anie.201600896
Authors
- Publisher:
- Wiley
- Journal:
- Angewandte Chemie (International ed. in English) More from this journal
- Volume:
- 55
- Issue:
- 16
- Pages:
- 4992–4996
- Publication date:
- 2016-03-01
- DOI:
- EISSN:
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1521-3773
- ISSN:
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1433-7851
- Language:
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English
- Keywords:
- Pubs id:
-
pubs:609376
- UUID:
-
uuid:b03de06d-7013-4fa3-a1a3-18f07c960c59
- Local pid:
-
pubs:609376
- Source identifiers:
-
609376
- Deposit date:
-
2016-04-12
Terms of use
- Copyright holder:
- O'Hare
- Copyright date:
- 2016
- Notes:
- © 2016 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
- Licence:
- CC Attribution (CC BY)
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