- Abstract:
-
Reaction of Cp*MoCl4(1), or (Cp*MoCl2)2 (2), Cp* = η5-C5Me5, with BH3·THF ultimately generates the Mo(II) cluster (Cp*Mo)2B5H9 (7), together with the Mo(III) species (Cp*MoCl)2B4H10, 4. Prereduction of 2 before reaction with BH3·THF yields only 7. The structure of 4 consists of two Cp*Mo units bridged by two chlorides and a [B2H5(B2H5)]2- ligand in which the two diboron moieties are connected by a B-B-B three center bond. Closer inspection of the reaction by 11B and 1H NMR reveals the existen...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ja973720n
-
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- Publisher:
- American Chemical Society
- Journal:
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Volume:
- 120
- Issue:
- 11
- Pages:
- 2586-2598
- Publication date:
- 1998-03-25
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- URN:
-
uuid:af8880fb-a17c-469d-8962-317027c6a9c9
- Source identifiers:
-
46075
- Local pid:
- pubs:46075
- Language:
- English
- Copyright date:
- 1998
Journal article
Synthesis of novel molybdaboranes from (eta(5)-C5R5)MoCln precursors (R=H,Me; n=1,2,4)
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