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Journal article

NO rotational orientation following 308 nm photodissociation of NO2.

Abstract:
The rotational angular momentum orientation and alignment of the NO fragments generated via linearly polarized 308 nm photodissociation of NO2 has been determined using laser induced fluorescence. By observing the dependence of the photofragment NO Doppler-resolved transition line shapes on experimental geometry, it has proved possible to determine multipole moments of the photofragment angular momentum distribution up to, and including, rank 3. The implications of the results for the mechanism of the dissociation are considered.
Publication status:
Published

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Publisher copy:
10.1103/physrevlett.86.2249

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Journal:
Physical Review Letters More from this journal
Volume:
86
Issue:
11
Pages:
2249-2252
Publication date:
2001-03-01
DOI:
EISSN:
1079-7114
ISSN:
0031-9007


Language:
English
Pubs id:
pubs:52456
UUID:
uuid:af7bf81b-3012-400d-a380-73cd1019583c
Local pid:
pubs:52456
Source identifiers:
52456
Deposit date:
2012-12-19

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