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On the reactivity of α-trifluoromethylstyrene in radical copolymerizations with various fluoroalkenes

Abstract:

The synthesis and radical co- and terpolymerizations of α-trifluoromethylstyrene (TFMST) with various fluorinated and hydrogenated comonomers are presented. The selected fluorinated comonomers were: vinylidene fluoride (VDF), chlorotrifluoroethylene (CTFE), 3,3,3-trifluoropropene (TFP), 1H,1H,2H,2H-perfluoro-1-decyl vinyl ether (FAVE-8), while the hydrogenated one was ethyl vinyl ether (EVE). Though the homopolymerization and most copolymerizations of TFMST failed, the radical terpolymerizati...

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Publication status:
Published
Peer review status:
Peer reviewed

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Authors


Walkowiak-Kulikowska, J More by this author
Boschet, F More by this author
More by this author
Department:
Merton College
Ameduri, B More by this author
National Science Centre, Poland More from this funder
Publisher:
Elsevier Publisher's website
Journal:
European Polymer Journal Journal website
Volume:
84
Pages:
612-621
Publication date:
2016-09-05
Acceptance date:
2016-09-23
DOI:
EISSN:
1873-1945
ISSN:
0014-3057
Pubs id:
pubs:657730
URN:
uri:af795968-62b8-4501-a56f-3d79036755d7
UUID:
uuid:af795968-62b8-4501-a56f-3d79036755d7
Local pid:
pubs:657730

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