Journal article icon

Journal article

Synthesis and isolation of [Fe@Ge(10)](3-): a pentagonal prismatic Zintl ion cage encapsulating an interstitial iron atom.

Abstract:

Reaction of an ethylenediamine (en) solution of the Zintl phase precursor K(4)Ge(9) with FeAr(2) (Ar = 2,6-Mes(2)C(6)H(3)) in the presence of 2,2,2-crypt (4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) yielded the endohedral Zintl ion [Fe@Ge(10)](3-) (1) which was crystallographically characterized as a [K(2,2,2-crypt)](+) salt in [K(2,2,2-crypt)](3)[Fe@Ge(10)]*2en. This unprecedented Zintl ion exhibits a pentagonal prismatic 10-atom germanium cage with an interstitial iron atom ...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/ja900055j

Authors


Denning, MS More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Journal of the American Chemical Society
Volume:
131
Issue:
8
Pages:
2802-2803
Publication date:
2009-03-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:af407090-79e0-43e0-849a-81809d6e1236
Source identifiers:
34590
Local pid:
pubs:34590
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP