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The Dynamics of N(2)-O(3) and N(2)-SO(2) Probed by Microwave Spectroscopy.

Abstract:

The microwave spectra of N(2)-O(3) and N(2)-SO(2) have been recorded in the 6-18 GHz range using a pulsed-nozzle, Fourier transform microwave spectrometer. C-type transitions have been observed for both complexes which are slightly shifted by internal tunneling motions of the O(3) or SO(2) moieties. In addition, unshifted a-type transitions have been observed for N(2)-O(3). The nuclear hyperfine pattern is typical of equivalent nitrogen nuclei. Two sets of rotational and hyperfine constants a...

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Publication status:
Published

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Publisher copy:
10.1006/jmsp.1999.8020

Authors


Connelly, JP More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
Journal of molecular spectroscopy
Volume:
199
Issue:
2
Pages:
205-216
Publication date:
2000-02-05
DOI:
ISSN:
0022-2852
URN:
uuid:ae45ff86-aba9-46a9-a952-c9865d4b7fc5
Source identifiers:
31602
Local pid:
pubs:31602
Language:
English

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