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Research update: Strategies for improving the stability of perovskite solar cells

Abstract:
The power-conversion efficiency of perovskite solar cells has soared up to 22.1% earlier this year. Within merely five years, the perovskite solar cell can now compete on efficiency with inorganic thin-film technologies, making it the most promising of the new, emerging photovoltaic solar cell technologies. The next grand challenge is now the aspect of stability. The hydrophilicity and volatility of the organic methylammonium makes the work-horse material methylammonium lead iodide vulnerable to degradation through humidity and heat. Additionally, ultraviolet radiation and oxygen constitute stressors which can deteriorate the device performance. There are two fundamental strategies to increasing the device stability: developing protective layers around the vulnerable perovskite absorber and developing a more resilient perovskite absorber. The most important reports in literature are summarized and analyzed here, letting us conclude that any long-term stability, on par with that of inorganic thin-film technologies, is only possible with a more resilient perovskite incorporated in a highly protective device design.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.4961210

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author


Publisher:
AIP Publishing
Journal:
APL Materials More from this journal
Volume:
4
Issue:
9
Article number:
091503
Publication date:
2016-09-01
Acceptance date:
2016-08-03
DOI:
ISSN:
2166-532X


Pubs id:
pubs:637488
UUID:
uuid:add58d65-4a1c-4f3d-8344-7648a1ab4513
Local pid:
pubs:637488
Source identifiers:
637488
Deposit date:
2016-08-05

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