Journal article
Electronic structures of Pd(II) dimers.
- Abstract:
-
The Pd(II) dimers [(2-phenylpyridine)Pd(mu-X)](2) and [(2-p-tolylpyridine)Pd(mu-X)](2) (X = OAc or TFA) do not exhibit the expected planar geometry (of approximate D(2h) symmetry) but instead resemble an open "clamshell" in which the acetate ligands are perpendicular to the plane containing the Pd atoms and 2-arylpyridine ligands, with the Pd atoms brought quite close to one another (approximate distance 2.85 A). The molecules adopt this unusual geometry in part because of a d(8)-d(8) bonding...
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- Publication status:
- Published
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- Publisher copy:
- 10.1021/ic902189g
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Authors
Bibliographic Details
- Journal:
- Inorganic chemistry
- Volume:
- 49
- Issue:
- 4
- Pages:
- 1801-1810
- Publication date:
- 2010-02-01
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- Source identifiers:
-
49037
Item Description
- Language:
- English
- Pubs id:
-
pubs:49037
- UUID:
-
uuid:ab8c33ec-9d62-4a84-a446-a8de4bc43238
- Local pid:
- pubs:49037
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2010
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