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Boryl substituted group 13 metallylenes: complexes with an iron carbonyl fragment.

Abstract:
The first examples of boryl substituted aluminylene and gallylene complexes, [(DAB)B(THF)Al{Fe(CO)3(μ-CO)}]2 and [(DAB)BGa{μ-Fe(CO)4}]2 (DAB = {(C6H3Pr(i)2-2,6)NCH}2) have been prepared by reduction of MX2(THF){B(DAB)} (M = Al or Ga, X = Cl or Br) with K2[Fe(CO)4]. Spectroscopic and crystallographic analyses of the compounds show them to be structurally distinct dimers, the latter of which possesses a close GaGa separation that computational analyses reveal has negligible bonding character.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c6cc08449d

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Institution:
University of Oxford
Oxford college:
Queens College
Role:
Author
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Funding agency for:
Aldridge, S
Grant:
Feodor Lynen Research fellowship
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Funding agency for:
Aldridge, S
Grant:
Feodor Lynen Research fellowship
Australian Research Council More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
53
Issue:
1
Pages:
149-152
Publication date:
2016-11-01
Acceptance date:
2016-11-03
DOI:
ISSN:
1364-548X
Source identifiers:
658019
Language:
English
Keywords:
Pubs id:
pubs:658019
UUID:
uuid:aa8d1f38-5636-4316-ada9-338f57b8a64b
Local pid:
pubs:658019
Deposit date:
2017-03-03

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