Journal article
Boryl substituted group 13 metallylenes: complexes with an iron carbonyl fragment.
- Abstract:
- The first examples of boryl substituted aluminylene and gallylene complexes, [(DAB)B(THF)Al{Fe(CO)3(μ-CO)}]2 and [(DAB)BGa{μ-Fe(CO)4}]2 (DAB = {(C6H3Pr(i)2-2,6)NCH}2) have been prepared by reduction of MX2(THF){B(DAB)} (M = Al or Ga, X = Cl or Br) with K2[Fe(CO)4]. Spectroscopic and crystallographic analyses of the compounds show them to be structurally distinct dimers, the latter of which possesses a close GaGa separation that computational analyses reveal has negligible bonding character.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Accepted manuscript, pdf, 1.0MB, Terms of use)
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- Publisher copy:
- 10.1039/c6cc08449d
Authors
+ Alexander von Humboldt Stiftung
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- Funding agency for:
- Aldridge, S
- Grant:
- Feodor Lynen Research fellowship
+ Australian Research Council
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- Funding agency for:
- Aldridge, S
- Grant:
- Feodor Lynen Research fellowship
+ U.S. Air Force Asian Office of Aerospace Research and Development
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- Grant:
- FA2386-14‐1‐4043
- Publisher:
- Royal Society of Chemistry
- Journal:
- Chemical Communications More from this journal
- Volume:
- 53
- Issue:
- 1
- Pages:
- 149-152
- Publication date:
- 2016-11-01
- Acceptance date:
- 2016-11-03
- DOI:
- ISSN:
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1364-548X
- Language:
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English
- Keywords:
- Pubs id:
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pubs:658019
- UUID:
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uuid:aa8d1f38-5636-4316-ada9-338f57b8a64b
- Local pid:
-
pubs:658019
- Source identifiers:
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658019
- Deposit date:
-
2017-03-03
Terms of use
- Copyright holder:
- Royal Society of Chemistry
- Copyright date:
- 2016
- Notes:
- © The Royal Society of Chemistry 2017
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