Journal article
Boryl substituted group 13 metallylenes: complexes with an iron carbonyl fragment.
- Abstract:
- The first examples of boryl substituted aluminylene and gallylene complexes, [(DAB)B(THF)Al{Fe(CO)3(μ-CO)}]2 and [(DAB)BGa{μ-Fe(CO)4}]2 (DAB = {(C6H3Pr(i)2-2,6)NCH}2) have been prepared by reduction of MX2(THF){B(DAB)} (M = Al or Ga, X = Cl or Br) with K2[Fe(CO)4]. Spectroscopic and crystallographic analyses of the compounds show them to be structurally distinct dimers, the latter of which possesses a close GaGa separation that computational analyses reveal has negligible bonding character.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Accepted manuscript, pdf, 1.0MB)
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- Publisher copy:
- 10.1039/c6cc08449d
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Authors
Funding
+ Australian Research Council
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Funding agency for:
Aldridge, S
Grant:
Feodor Lynen Research fellowship
+ Alexander von Humboldt Stiftung
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Funding agency for:
Aldridge, S
Grant:
Feodor Lynen Research fellowship
+ U.S. Air Force Asian Office of Aerospace Research and Development
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Grant:
FA2386-14‐1‐4043
Australian Research Council
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Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Chemical Communications Journal website
- Volume:
- 53
- Issue:
- 1
- Pages:
- 149-152
- Publication date:
- 2016-11-01
- Acceptance date:
- 2016-11-03
- DOI:
- ISSN:
-
1364-548X
- Source identifiers:
-
658019
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:658019
- UUID:
-
uuid:aa8d1f38-5636-4316-ada9-338f57b8a64b
- Local pid:
- pubs:658019
- Deposit date:
- 2017-03-03
Terms of use
- Copyright holder:
- Royal Society of Chemistry
- Copyright date:
- 2016
- Notes:
- © The Royal Society of Chemistry 2017
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