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Fluorous synthesis of allylic fluorides: C-F bond formation as the detagging process.

Abstract:
A novel fluorous tagging-detagging strategy has been developed featuring a fluorination as the detagging process; fluorous allylsilanes were prepared by cross-metathesis and subsequently subjected to electrophilic fluorodesilylation; Selectfluor was used as the detagging reagent; the resulting allylic fluorides were successfully purified by fluorous solid phase extraction.
Publication status:
Published

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Publisher copy:
10.1039/b804484h

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Chemical Communications
Issue:
31
Pages:
3622-3624
Publication date:
2008-08-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
34332
Language:
English
Keywords:
Pubs id:
pubs:34332
UUID:
uuid:aa75f512-7d85-4980-9e22-7899f7aa6d37
Local pid:
pubs:34332
Deposit date:
2012-12-19

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