Journal article
Novel determination of surface temperature of lithium hydride hydrolysis using DRIFT spectroscopy
- Abstract:
-
Diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy has been used to show how increasing temperature causes the hydroxyl band of LiOH to shift linearly and reversibly towards lower wavenumbers. The band shift with temperature was used to determine the surface temperature of LiH when exposed to water vapour at 158, 317, 793 and >1900 Pa (5%, 10%, 25% and >60% relative humidity), the exothermic hydrolysis reaction resulting in surface temperature increases of up to 50 °C. ...
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- Publisher copy:
- 10.1016/j.jnucmat.2008.07.010
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Authors
Bibliographic Details
- Journal:
- Journal of Nuclear Materials
- Volume:
- 381
- Issue:
- 3
- Pages:
- 223-230
- Publication date:
- 2008-11-15
- DOI:
- ISSN:
-
0022-3115
- Source identifiers:
-
180265
Item Description
- Language:
- English
- Pubs id:
-
pubs:180265
- UUID:
-
uuid:a94c398a-7975-4274-88c5-c67333289932
- Local pid:
- pubs:180265
- Deposit date:
- 2013-02-20
Terms of use
- Copyright date:
- 2008
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