Journal article
Synthesis of five‐porphyrin nanorings by using ferrocene and corannulene templates
- Abstract:
- The smallest and most strained member of a family of π‐conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl templates based on ferrocene and corannulene. Both templates are effective for directing the synthesis of the butadiyne‐linked cyclic pentamer, despite the fact that the radii of their N5 donor sets are too small by 0.5 Å and 0.9 Å, respectively (from DFT calculations). The five‐porphyrin nanoring exhibits a structured absorption spectrum and its fluorescence extends to 1200 nm, reflecting strong π conjugation and Herzberg–Teller vibronic coupling.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Access Document
- Files:
-
-
(Preview, Version of record, pdf, 2.0MB, Terms of use)
-
- Publisher copy:
- 10.1002/ange.201602909
Authors
- Publisher:
- John Wiley and Sons, Ltd.
- Journal:
- Angewandte Chemie More from this journal
- Volume:
- 128
- Issue:
- 29
- Pages:
- 8498-8502
- Publication date:
- 2016-05-23
- Acceptance date:
- 2016-04-14
- DOI:
- EISSN:
-
1521-3757
- ISSN:
-
0044-8249
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:823947
- UUID:
-
uuid:a8efd0de-719f-4602-8b1d-1486c9d73609
- Local pid:
-
pubs:823947
- Source identifiers:
-
823947
- Deposit date:
-
2019-01-24
Terms of use
- Copyright holder:
- Liu et al
- Copyright date:
- 2016
- Notes:
-
© 2016 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA.
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
- Licence:
- CC Attribution (CC BY)
If you are the owner of this record, you can report an update to it here: Report update to this record