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Journal article

Synthesis of five‐porphyrin nanorings by using ferrocene and corannulene templates

Abstract:

The smallest and most strained member of a family of π‐conjugated cyclic porphyrin oligomers was synthesized by using pentapyridyl templates based on ferrocene and corannulene. Both templates are effective for directing the synthesis of the butadiyne‐linked cyclic pentamer, despite the fact that the radii of their N5 donor sets are too small by 0.5 Å and 0.9 Å, respectively (from DFT calculations). The five‐porphyrin nanoring exhibits a structured absorption spectrum and its fluorescence exte...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/ange.201602909

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Publisher:
John Wiley and Sons, Ltd. Publisher's website
Journal:
Angewandte Chemie Journal website
Volume:
128
Issue:
29
Pages:
8498-8502
Publication date:
2016-05-23
Acceptance date:
2016-04-14
DOI:
EISSN:
1521-3757
ISSN:
0044-8249
Language:
English
Keywords:
Pubs id:
pubs:823947
UUID:
uuid:a8efd0de-719f-4602-8b1d-1486c9d73609
Local pid:
pubs:823947
Source identifiers:
823947
Deposit date:
2019-01-24

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