Journal article
Copper-catalyzed synthesis of activated sulfonate esters from boronic acids, DABSO, and pentafluorophenol
- Abstract:
- The synthesis of pentafluorophenyl (PFP) sulfonate esters based on the Pd-catalyzed sulfination of aryl and heteroaryl boronic acids is reported. The sulfinate intermediates are converted in situ to the corresponding sulfonate esters using a copper-catalyzed oxidative process, providing a broad range of PFP esters in good yields.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
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(Preview, Accepted manuscript, pdf, 383.4KB, Terms of use)
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(Preview, Supplementary materials, pdf, 6.6MB, Terms of use)
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- Publisher copy:
- 10.1021/acs.orglett.8b02445
Authors
- Publisher:
- American Chemical Society
- Journal:
- Organic Letters More from this journal
- Volume:
- 20
- Issue:
- 17
- Pages:
- 5493–5496
- Publication date:
- 2018-08-28
- Acceptance date:
- 2018-08-22
- DOI:
- EISSN:
-
1523-7052
- ISSN:
-
1523-7060
- Language:
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English
- Pubs id:
-
pubs:910888
- UUID:
-
uuid:a8d070dd-a484-46e4-a29f-9fafdb0f2b51
- Local pid:
-
pubs:910888
- Source identifiers:
-
910888
- Deposit date:
-
2018-08-29
- ARK identifier:
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2018
- Rights statement:
- Copyright © 2018 American Chemical Society
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from American Chemical Society at https://dx.doi.org/10.1021/acs.orglett.8b02445
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