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INTRAMOLECULAR ELECTRON-TRANSFER IN PERIPHERALLY METALATED TETRAPHENYL PORPHYRIN DERIVATIVES CONTAINING MOLYBDENUM MONONITROSYL REDOX CENTERS

Abstract:: Picosecond laser spectroscopy measurements on the novel complexes [Mo(NO)(L)Cl(Etpp)] [Etpp = 5-(E-substituted phenyl-10,15,20-triphenylporphyrin; L = hydrotris(3,5-dimethylpyrazol-1-yl)borate, E = para-O, meta-O, ortho-O; para-NH] indicate that the observed fluorescence quenching in these compounds is due to fast (τ < 30 ps) intramolecular charge separation to produce transient species with lifetimes in the range 120-290 ps.

Publication status:: Published

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APA Style

Rowley, N., Kurek, S., George, M., Hubig, S., Beer, P., Jones, C., Kelly, J., & Mccleverty, J. (1992). INTRAMOLECULAR ELECTRON-TRANSFER IN PERIPHERALLY METALATED TETRAPHENYL PORPHYRIN DERIVATIVES CONTAINING MOLYBDENUM MONONITROSYL REDOX CENTERS. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 6, 497–499.

MLA Style

Rowley, N., et al. “INTRAMOLECULAR ELECTRON-TRANSFER IN PERIPHERALLY METALATED TETRAPHENYL PORPHYRIN DERIVATIVES CONTAINING MOLYBDENUM MONONITROSYL REDOX CENTERS.” JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, no. 6, 1992, pp. 497–99.

Chicago Style

Rowley, N, S Kurek, M George, S Hubig, P Beer, C Jones, J Kelly, and J Mccleverty. 1992. “INTRAMOLECULAR ELECTRON-TRANSFER IN PERIPHERALLY METALATED TETRAPHENYL PORPHYRIN DERIVATIVES CONTAINING MOLYBDENUM MONONITROSYL REDOX CENTERS.” JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, no. 6: 497–99.
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Publisher copy:: 10.1039/c39920000497

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Bibliographic Details

Journal:: JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Issue:: 6
Pages:: 497-499
Publication date:: 1992-03-15
DOI:: 10.1039/c39920000497
ISSN:: 0022-4936

Item Description

Language:: English
Pubs id:: pubs:43814
UUID:: uuid:a758ec20-d633-4f9c-ab37-85f08e5aabf7
Local pid:: pubs:43814
Source identifiers:: 43814
Deposit date:: 2012-12-19

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Copyright date:: 1992

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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