Journal article icon

Journal article

Mechanistic determination using arrays of variable sized channel microband electrodes: The oxidation of 2,3,7,8-tetramethoxythianthrene in the presence of pyridine in acetonitrile solution

Abstract:

2-Dimensional amperometry'' using arrays of gold channel microband electrodes is applied to the oxidation of 2,3,7,8-tetramethoxythianthrene (TMT) and to the characterization of the follow-up kinetics of the resulting radical cation with pyridine. In the absence of pyridine the reaction is consistent with an E mechanism and a value of 1.3 × 10-5 cm2s-1 is obtained for the diffusion coefficient of TMT. In the presence of pyridine the experimental results are consistent with a DISP2 mechanism w...

Expand abstract
Publication status:
Published

Actions


Access Document


Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Expand authors...
Journal:
ELECTROANALYSIS
Volume:
10
Issue:
10
Pages:
685-690
Publication date:
1998-08-05
DOI:
EISSN:
1521-4109
ISSN:
1040-0397
URN:
uuid:a71c13b6-19ae-4d84-a4e2-9b630bc0d6c4
Source identifiers:
36626
Local pid:
pubs:36626

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP