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Magnetostriction-driven ground-state stabilization in 2H perovskites

Abstract:
The magnetic ground state of Sr3ARuO6, with A=(Li,Na), is studied using neutron diffraction, resonant x-ray scattering, and laboratory characterization measurements of high-quality crystals. Combining these results allows us to observe the onset of long-range magnetic order and distinguish the symmetrically allowed magnetic models, identifying in-plane antiferromagnetic moments and a small ferromagnetic component along the c axis. While the existence of magnetic domains masks the particular in-plane direction of the moments, it has been possible to elucidate the ground state using symmetry considerations. We find that due to the lack of local anisotropy, antisymmetric exchange interactions control the magnetic order, first through structural distortions that couple to in-plane antiferromagnetic moments and second through a high-order magnetoelastic coupling that lifts the degeneracy of the in-plane moments. The symmetry considerations used to rationalize the magnetic ground state are very general and will apply to many systems in this family, such as Ca3ARuO6, with A=(Li,Na), and Ca3LiOsO6 whose magnetic ground states are still not completely understood.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1103/PhysRevB.94.134404

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author


Publisher:
American Physical Society
Journal:
Physical Review B More from this journal
Volume:
94
Issue:
13
Pages:
134404
Publication date:
2016-10-01
Acceptance date:
2016-09-07
DOI:
ISSN:
2469-9950 and 2469-9969


Keywords:
Pubs id:
pubs:656482
UUID:
uuid:a6ef3941-4b71-4ccb-970a-ebae77d9e594
Local pid:
pubs:656482
Source identifiers:
656482
Deposit date:
2016-11-15

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